Title Information
Title
Closure Temperature and Closure Pressure in Bi-Mineralic Systems with Applications to REE-in-Two-Mineral Thermobarometers
Name: Personal
Name Part
Yao, Lijing
Role
Role Term: Text
creator
Origin Information
Copyright Date
2015
Physical Description
Extent
xviii, 255 p.
digitalOrigin
born digital
Note
Thesis (Ph.D. -- Brown University (2015)
Name: Personal
Name Part
Liang, Yan
Role
Role Term: Text
Director
Name: Personal
Name Part
Hirth, Greg
Role
Role Term: Text
Reader
Name: Personal
Name Part
Parman, Stephen
Role
Role Term: Text
Reader
Name: Personal
Name Part
Parmentier, Marc
Role
Role Term: Text
Reader
Name: Personal
Name Part
Saal, Alberto
Role
Role Term: Text
Reader
Name: Corporate
Name Part
Brown University. Geological Sciences
Role
Role Term: Text
sponsor
Genre (aat)
theses
Abstract
Thermal evolution of the planet interior is a fundamental problem in Earth and planetary sciences. Geothermobarometers and geospeedometers are powerful tools in studying the thermal history of igneous and metamorphics rocks from the interior of the planets. These tools are developed based on the exchange of elements or isotope ratios of interest between coexisting minerals. The exchange reactions for major elements and partitioning for trace elements with changing temperature (T) and pressure (P) require better understanding of diffusive re-distribution of the elements in the coexisting minerals. Here I conducted numerical simulations of diffusive re-distribution of major and trace elements in cooling and heating bi-mineralic systems using a finite difference method. Applying the diffusion model to the diffusive exchange of REE in two-pyroxene and garnet-clinopyroxene systems, I found that temperatures (TREE) and pressures (PREE) derived from the REE-in-two-mineral thermobarometers (Liang et al., 2013; Sun and Liang, 2015) are essentially the same as the average REE closure temperature and closure pressure defined by the effective partition coefficient following Dodson’s concept of closure temperature (1973, 1976), and are consistent with the prescribed P-T paths (Chapters 1 and 2). Because of the fast diffusion rates of major elements in minerals, diffusion modeling with coupled major elements and REE demonstrates a later closure time of major elements in the bi-mineral systems. The decoupling in closure time between major elements and REE can result in ±20°C uncertainties in REE closure temperatures calculated using the REE-in-two-pyroxene thermometer (Chapter 3). In additional, I have also conducted experimental and theoretical studies of REE partitioning between low-Ca pyroxene and basaltic melts, which is presented in Chapter 4.
Subject
Topic
closure temperature
Subject
Topic
closure pressure
Subject
Topic
bi-mineralic systems
Subject
Topic
REE-in-two-pyroxene thermometer
Subject
Topic
REE-in-garnet-clinopyroxene thermobarometer
Record Information
Record Content Source (marcorg)
RPB
Record Creation Date (encoding="iso8601")
20150601
Language
Language Term: Code (ISO639-2B)
eng
Language Term: Text
English
Identifier: DOI
10.7301/Z0H70D6S
Access Condition: rights statement (href="http://rightsstatements.org/vocab/InC/1.0/")
In Copyright
Access Condition: restriction on access
Collection is open for research.
Type of Resource (primo)
dissertations